Centers & Labs

RIKEN Center for Advanced Photonics

Ultrafast Spectroscopy Research Team

Team Leader: Tahei Tahara (D.Sci.)
Tahei  Tahara(D.Sci.)

We develop advanced spectroscopic methods based on the "extreme" optical technology, and carry out fundamental studies for controlling chemical reactions and material functions. We pursue the basic knowledge for developing novel functional materials by investigating the elementary processes that occur in fundamental molecules, complex molecules, and heterogeneous molecular systems. Using the most advanced spectroscopy, we observe and control the motion and function of the molecules.

Main Research Field

Chemistry

Related Research Fields

Biology

Keywords

  • Ultrafast spectroscopy
  • Nonlinear spectroscopy
  • Single molecule spectroscopy
  • Reaction dynamics
  • Interface

Selected Publications

  1. Kuramochi, H. Takeuchi, S. Yonezawa, K. Kamikubo, H. Kataoka M. Tahara, T.:
    "Probing the early stages of photoreception in photoactive yellow protein with ultrafast time-domain Raman spectroscopy"
    Nat. Chem., 9, 660 (2017).
  2. Sartin, M. Kondo, K. Yoshizawa, M. Takeuchi, S. Tahara, T.:
    "Local environment inside a novel aromatic micelle investigated by steady-state and femtosecond fluorescence spectroscopy of an encapsulated solvatochromic probe"
    Phys. Chem. Chem. Phys. 19, 757 (2017).
  3. "Femtosecond hydrogen-bond dynamics of bulk-like and bound water at positively and negatively charged lipid interfaces revealed by 2D HD-VSFG spectroscopy"
    Angew. Chem. Int. Ed. 55, 10621 (2016).
  4. Matsuzaki, K. Kusaka, R. Nihonyanagi, S. Yamaguchi, S. Nagata, T. Tahara, T.:
    "Partially hydrated electrons at the air/water interface observed by UV-excited time-resolved heterodyne-detected vibrational sum frequency generation spectroscopy"
    J. Am. Chem. Soc. 138, 7551 (2016).
  5. Kuramochi, H. Takeuchi, S. Tahara, T.:
    "Femtosecond time-resolved impulsive stimulated Raman spectroscopy using sub-7-fs pulses: Apparatus and applications"
    Rev. Sci. Instrum. 87, 043107 (2016).
  6. Tahara, S. Takeuchi, S. Abe-Yoshizumi, R. Inoue, K. Ohtani, H. Kandori, H. Tahara, T.:
    "Ultrafast photoreaction dynamics of a light-driven sodium-ion-pumping retinal protein from Krokinobacter eikastus revealed by femtosecond time-resolved absorption spectroscopy"
    J. Phys. Chem. Lett. 6, 4481 (2015).
  7. Singh, P. C. Nihonyanagi, S. Yamaguchi, S. Tahara T.:
    "Interfacial water in the vicinity of a positively charged interface studied by steady-state and time-resolved heterodyne-detected vibrational sum frequency generation"
    J. Chem. Phys. 141, 18C527 (2014).
  8. Iwamura, M. Takeuchi, S. Tahara, T.:
    "Substituent Effect on the Photoinduced Structural Change of Cu(I) Complexes Observed by Femtosecond Emission Spectroscopy"
    Phys. Chem. Chem. Phys. 16, 4143 (2014).
  9. Singh, P. C. Nihonyanagi, S. Yamaguchi, S. Tahara T.:
    "Ultrafast vibrational dynamics of hydrogen bond network terminated at the air/water interface: A two-dimensional heterodyne-detected vibrational sum frequency generation study"
    J. Chem. Phys. 139, 161101 (2013).
  10. Iwamura, M. Nozaki, K. Takeuchi, S. Tahara, T.:
    "Real-time Observation of Tight Au-Au Bond Formation and Relevant Coherent Motion upon Photoexcitation of [Au(CN)2−] Oligomers"
    J. Am. Chem. Soc. 135, 538 (2013).

Lab Members

Principal Investigator

Tahei Tahara
Team Leader

Core Members

Satoshi Takeuchi
Senior Research Scientist
Kunihiko Ishii
Senior Research Scientist
Satoshi Nihonyanagi
Senior Research Scientist
Hikaru Kuramochi
Research Scientist
Ahmed Mohammed
Postdoctoral Researcher

Contact information

2-1 Hirosawa, Wako, Saitama 351-0198, Japan

Email: tahei [at] riken.jp

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