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Supramolecular Science Laboratory
Chief Scientist: Katsumi MIDORIKAWA (D.Eng.)
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Research Areas

Optical and electronic properties of supramolecular systems such as hyper branched polymers, dendrimers and cyclic oligomers are studied from the viewpoint of energy states and topological structures. In addition to the fundamental understandings of structure-property-relationship, applications to optical information processing and soft-optoelectronics devices are important targets of the research. For the development of switchable soft-optoelectronics materials, changes of the electronic state with molecular recognition, the self-tuning mechanism of supramolecules and collective motion based on molecular-structural changes are characterized using nonlinear optical spectroscopy. Spatial light modulators and hologram display devices are also developed based on photoinduced refractive index changes.

Research Subject

  1. Development of multifunctional supramolecules and soft-optoelectronics materials
  2. Elucidation of supramolecular dynamics using nonlinear optical spectroscopy
  3. Application of supramolecular photonics to image processing

Press release

April 15, 2009
Success in NMR-based analysis of the unique and complex three dimensional structure of natural mucin via application of analytical techniques developed through the study of the new material qniumucin from jellyfish

RIKEN RESEARCH

September 28, 2007
Getting out of a jam with jellies
The isolation of a promising new protein could help reverse the economic damage being done by exploding jellyfish populations New Window

List of Selected Publications

  1. Fujihara, T., Sassa, T., Kawata, T., Mamiya, J., Muto, T., and Umegaki, S.:
    "Simplified procedure for interferometric determination of electric properties of Low-Tg photorefractive polymer.
    J. Appl. Phys. 107, 023112 (2010).
  2. Ribierre, J. C., Watanabe, S., Matsumoto, M., Muto, T., and Aoyama, T.:
    "Majority carrier type conversion in solution-processed organic transistors and flexible complementary logic circuits.
    Appl. Phys. Lett. 96, 083303 (2010).
  3. Kawamoto, M., Sassa, T., and Wada, T.:
    "Photoinduced Control over the Self-Organized Orientation of Amorphous Molecular Materials Using Polarized Light."
    J. Phys. Chem. B 114, pp. 1227-1232 (2010).
  4. Hosokai, T., Aoyama, T., Kobayashi, T., Nakao, A., and Matsumoto, S.:
    "Photovoltaic properties of bisazomethine dye thin films."
    Chem. Phys. Lett. 487, pp. 77-80 (2010).
  5. Tajima, Y., Numata,Y., and Kawashima, J.:
    "The Substituent Effect on the Reduction Potentials of Heterocyclic-Fused [60]Fullerene Derivatives."
    ECS Trans. 16, pp. 33-43 (2009).
  6. Takaishi, K., Kawamoto, M., Tsubaki, K., and Wada, T.:
    "Photoswitching of Dextro/Levo Rotation with Axially Chiral Binaphthyls Linked to an Azobenzene."
    J. Org. Chem. 74, pp. 5723-5726 (2009).
  7. Uzawa, J., Urai, M., Baba, T., Seki, H., Taniguchi, K., and Ushida, K.:
    "NMR study on a novel mucin from jellyfish in natural abundance, qniumucin from Aurelia aurita."
    J. Nat. Prod. 72, pp. 818-823 (2009).
  8. Ghosh, S. K., Ichiyanagi, N., Odabayasi, H., Yoshino, A., Takayoshi, T., and O'Connor,C.J.:
    "Effect of Hydration on the Very Slow Droplet-Lamellar Transition in Dioleylsulfosuccinate/Decane/Water System- A Small Angle X-ray Scattering Study."
    Bull. Chem. Soc. Jpn. 82, pp. 664-674 (2009).
  9. Ikeda, S., Kumagai, H., Ooi, H., Konishi, K., Hiyoshi, H., and Wada, T.:
    "Precise Determination of the First Hyperpolarizability of a Fluorescent Triindole Derivative with Dicyanovinyl Groups by the Deconvolution Method."
    Chem. Phys. Lett. 458, pp. 337-340 (2008).