Masayoshi NISHIURA
Birth: 12 September, 1971
Tel: +81-(0)48-467-9390
Fax: +81-(0)48-462-4665
E-mail:
| 西浦 正芳 Masayoshi NISHIURA Birth: 12 September, 1971 Tel: +81-(0)48-467-9390 Fax: +81-(0)48-462-4665 E-mail: |
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| Curriculum Vitae | ||
| >> Japanese | ||
| Education: | ||
| 1995 | B.Sc. | Faculty of Science, Chiba University (Japan) |
| 1997 | M.Sc. | Graduate School of Science, Chiba University (Japan) (Supervisor: Prof. Tsuneo Imamoto) |
| 2000 | Ph.D. | Graduate School of Science and Technology, Chiba University (Japan) (Supervisor: Prof. Tsuneo Imamoto) |
| Research and professional experience: | |
| 2000-2002 | Special Predoctoral Researcher, Organometallic Chemistry Laboratory, RIKEN |
| 2002 |
Research Scientist, Organometallic Chemistry Laboratory, RIKEN (Director: Dr. Zhaomin Hou) |
| 2009-present | Senior Research Scientist, Organometallic Chemistry Laboratory, RIKEN (Director: Dr. Zhaomin Hou) |
| Honor: | |
| 2009 | RIKEN Research Incentive Award |
| 2011 | Progress Award in Synthetic Organic Chemistry, Japan |
| Original Publications | |
| · | "Rare Earth Metal Boryl Complexes: Synthesis, Structure, and Insertion of a Carbodiimide and Carbon Monoxide", S. Li, J. Cheng, Y. Chen, M. Nishiura, Z. Hou, Angew. Chem. Int. Ed., 50, 6360-6363 (2011). |
| · | "Ln4(CH2)4 Cubane-Type Rare Earth Methylidene Complexes Consisting of "(C5Me4SiMe3)" Units (Ln = Tm, Lu)", W. Zhang, Z. Wang, M. Nishiura, Z. Xi, Z. Hou, J. Am. Chem. Soc. 133, 5712-5715(2011). |
| · | "Tetra-, Penta-, and Hexanuclear Yttrium Hydride Clusters from Half-Sandwich Bis(aminobenzyl) Complexes Containing Various Cyclopentadienyl Ligands", T. Shima, M. Nishiura, Z. Hou, Organometallics, 30, 2513-2524(2011). |
| · | "Synthesis, Structure and Efficient Electroluminescence of a Heteroleptic Dipyridylamido/ Bis(pyridylphenyl)iridium(III) Complex", V. K. Rai, M. Nishiura, M. Takimoto, Z. Hou, Chem. Commun. 47, 5726-5728(2011). |
| · | "Cycloterpolymerization of 1,6-Heptadiene with Ethylene and Styrene Catalyzed by a THF-Free Half-Sandwich Scandium Complex", F. Guo, M. Nishiura, H. Koshino, Z. Hou, Macromolecules, 44,2400-2403(2011). |
| · | "Synthesis and Structures of the C5Me4SiMe3-Supported Polyhydride Complexes over the Full Size Range of the Rare Earth Series", M. Nishiura, J. Baldamus, T. Shima, K. Mori, Z. Hou, Chem.Eur.J. ,17 ,5033-5044(2011) |
| · | "Syndiospecific Living Copolymerization of Styrene with e-Caprolactone by Scandium Catalysts", L. Pan, K. Zhang, M. Nishiura, Z.Hou, Macromolecules,43, 9591-9593(2010). |
| · | "Novel Polymerization Catalysts and Hydride Clusters from Rare Earth Metal Dialkyls", M. Nishiura, Z. Hou, Nature Chem., 2, 257-268 (2010). |
| · | "Alternating and Random Copolymerization of Isoprene and Ethylene Catalyzed by Cationic Half-Sandwich Scandium Alkyls", X. Li, M. Nishiura, L. Hu, K. Mori, Z. Hou, J. Am. Chem. Soc., 131, 13870-13882 (2009). |
| · | "Synthesis of (Z)-1-Aza-1,3-enynes by the Cross-Coupling of Terminal Alkynes with Isocyanides Catalyzed by Rare-Earth Metal Complexes",W.-X. Zhang, M. Nishiura, Z. Hou, Angew. Chem. Int. Ed., 47, 9700-9703 (2008). |
| · | "Half-Sandwich o-N,N-Dimethylaminobenzyl Complexes over the Full Size Range of Group 3 and Lanthanide Metals. Synthesis, Structural Characterization, and Catalysis of Phosphine PH Bond Addition to Carbodiimides",W.-X. Zhang, M. Nishiura, T. Mashiko, Z. Hou, Chem. Eur. J., 14, 2167-2179 (2008). |
| · | "Carboxylation of Organoboronic Esters Catalyzed by N-Heterocyclic Carbene Copper(I) Complexes ", T. Ohishi, M. Nishiura, Z. Hou, Angew. Chem. Int. Ed. 47, 5792-5795 (2008). |
| · | "Cationic Scandium Allyl Complexes Bearing Mono(cyclopentadienyl) Ligands: Synthesis, Novel Structural Variety, and Olefin-Polymerization Catalysis",N. Yu, M. Nishiura, X. Li, Z. Xi, Z. Hou, Chem. Asian. J. 3, 1406-1414 (2008). |
| · | "Isoprene Polymerization with Yttrium Amidinate Catalyst: Switching the Regio- and Stereoselectivity by Addition of AlMe3"L. Zhang, M. Nishiura, M. Yuki, Y. Luo, Z. Hou, Angew. Chem., Int. Ed., 47, 2642-2645 (2008). |
| · | "Synthesis and Styrene Polymerisation Catalysis of η5- and η1-Pyrrolyl-Ligated Cationic Rare Earth Metal Aminobenzylcomplexes", M. Nishiura, T. mashiko, Z. Hou, Chem. Commun.,2019-2021(2008). |
| · | "Rare-Earth-Metal Mixed Hydride/Aryloxyide Complexes Bearing Mono(cyclopentadienyl) Ligands. Synthesis, CO2 fixation, and Catalysis on Copolymerization of CO2 with Cyclohexene Oxide", D. Cui, M. Nishiura, O. Tradif, Z. Hou, Organometallics, 27, 2428-2435 (2008). |
| · | "Catalytic Addition of Amine N-H Bonds to Carbodiimides by Half-Sandwich Rare Earth Metal Complexes: Efficient Synthesis of Substituted Guanidines through Amine Protonolysis of Rare Earth Metal Guanidinates", W. Zhang, M. Nishiura, Z. Hou,Chem. Eur. J., 13, 4037-4051(2007). |
| · | "Cationic Scandium Aminobenzyl Complexes. Synthesis, Structure and Unprecedented Catalysis of Copolymerization of 1-Hexene and Dicyclopentadiene", X. Li, M. Nishiura, K. Mori, T. Mashiko, Z. Hou, Chem. Commun., 4137-4139 (2007). |
| · | "π-Conjugated Aromatic Enynes as a Single-Emitting Component for White Electroluminescence", Y. Liu, M. Nishiura, Y. Wang, Z.Hou, J. Am. Chem. Soc., 128, 5592-5593 (2006). |
| · | Cationic Rare-Earth Polyhydrido Complexes. Synthesis, Structure, and Catalytic Activity for the cis 1,4-Selective Polymerization of 1,3-Cyclohexadiene", X. Li, J.Baldamus, M. Nishiura, O. Tardif, Z. Hou, Angew. Chem., Int. Ed., 45, 8184-8188 (2006). |
| · | "Alkali-Metal-Catalyzed Addition of Primary and Secondary Phosphines to Carbodiimides. A General and Efficient Route to Substituted Phosphaguanidines", W.-X. Zhang, M. Nishiura, Z.Hou, Chem.Commun, 3812-3814 (2006). |
| · | "Catalytic Addition of Terminal Alkynes to Carbodiimides by half-Sandwich Rare Earth Metal Complexes", W.-X. Zhang, M. Nishiura, Z. Hou, J. Am. Chem. Soc., 127, 16788-16789 (2005). |
| · | "Rare Earth Metal Imido Complexes. Unprecedented Reactions with Benzonitrile", D. Cui, M. Nishiura, Z. Hou, Angew. Chem., Int. Ed., 44, 959-962 (2005). |
| · | "Alternating Copolymerization of Cyclohexene Oxide and Carbon Dioxide Catalyzed by Organo Rare Earth Metal Complexes", D. Cui, M. Nishiura, Z. Hou, Macromolecules, 38, 4089-4095 (2005). |
| · | "A Novel Binuclear Samarium(II) Complex Bearing Mixed Cyclopentadienide/Siloxide Ligands: [(C5Me5)Sm{µ-OSi(OtBu)3}3Sm]. Synthesis, Structure, Electron-Transfer, and Unusual Metal-Coordination Reactions", M. Nishiura, Z. Hou, Y. Wakatsuki, Organometallics, 23, 1359-1368 (2004). |
| · | "Organolanthanide Catalyzed Regio- and Stereoselective Dimerization of Terminal Alkynes and Polymerization of Aromatic Diynes", M. Nishiura, Z. Hou, J. Mol. Cat. A, 213, 101-106 (2004). |
| · | "Rare Earth Alkyl and Hydride Complexes Bearing Silylene-Linked Cyclopentadienyl-Phosphido Ligands. Synthesis, Structures, and Catalysis in Olefin Hydrosilylation and Ethylene Polymerization", O. Tardif, M. Nishiura, Z. Hou, Tetrahedron, 59, 10525-10539 (2003). |
| · | "Isolation and Structural Characterization of a Polyhydrido Lanthanide Cluster Complex Consisting of "(C5Me4SiMe3)LuH2" Units", O. Tardif, M. Nishiura, and Z. Hou, Organometallics, 22, 1171-1173 (2003). |
| · | "Novel Z-Selective Head-to-Head Dimerization of Terminal Alkynes Catalyzed by Lanthanide Half-Metallocene Complexes", M. Nishiura, Z. Hou, Y. Wakatsuki, T. Yamaki, and T. Miyamoto, J. Am. Chem. Soc., 125, 1184-1185 (2003). |
| · | "Ultimately Specific 1,4-cis Polymerization of 1,3-Butadiene with a Novel Gadolinium Catalyst", S. Kaita, Z. Hou, M. Nishiura, Y. Doi, J. Kurazumi, A. Horiguchi, Y. Wakatsuki, Macromol. Rapid Commun., 24, 180-184 (2003). |
| · | "(Pentamethylcyclopentadienyl) lanthanide(II) Alkyl and Silyl Complexes: Synthesis, Structures, and Catalysis in Polymerization of Ethylene and Styrene", Z. Hou, Y. Zhang, M. Nishiura, and Y. Wakatsuki, Organometallics, 22, 129-135 (2003). |
| 略歴 | >> English |
| 1995年3月 | 千葉大学 理学部化学科 卒業 多元素化学研究室（今本恒雄 教授） |
| 1997年3月 | 千葉大学大学院 理学研究科 修士課程（化学専攻）修了 多元素化学研究室（今本恒雄 教授） |
| 2000年3月 | 千葉大学大学院自然科学研究科博士課程（多様性化学専攻）修了 多元素化学研究室（今本恒雄 教授） |
| 2000年4月 | 理化学研究所 基礎科学特別研究員 (若槻康雄 主任研究員） |
| 2002年10月 | 理化学研究所 研究員（中央研究所 侯有機金属化学研究室） |
| 2009年4月 〜現在 |
理化学研究所 専任研究員（基幹研究所 侯有機金属化学研究室） |
| 兼務 | |
| 2004年〜 | 北京大学化学院 客員助教授 |
| 2008年〜 | 大連理工大学 客員助教授 |
| 受賞 | |
| 2009年 | 理化学研究所研究奨励賞 |
| 2011年 | 有機合成化学協会奨励賞 |