Takanori SHIMA
Date of birth: June 6, 1972
Telephone number: +81-48-467-9380
Fax number: +81-48-462-9391
Email address:
| 島 隆則 Takanori SHIMA Date of birth: June 6, 1972 Telephone number: +81-48-467-9380 Fax number: +81-48-462-9391 Email address: |
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| Curriculum Vitae | ||
| >> Japanese | ||
| Education: | ||
| 1996 | B.Sc. | Chemistry, 1996, Tokyo Institute of Technology (Japan) |
| 1998 | M.Sc. | Chemistry, 1998, Tokyo Institute of Technology (Japan) (Supervisor: Prof. Hiroharu Suzuki) |
| 2001 | Ph.D. | Chemistry, 2001, Tokyo Institute of Technology (Japan) (Supervisor: Prof. Hiroharu Suzuki) |
| Research and professional experience: | |
| 1998-2001 | Research Fellow of the Japan Society for the Promotion of Science |
| 2001-2002 | Postdoctoral Fellow of Japan Science and Technology Corporation (JST) (Prof. Hiroharu Suzuki) |
| 2003-2004 | Research Fellow of Humboldt Foundation from 2003 to 2004 Prof. John, A. Gladysz (Universitaet fuer Erlangen-Nuernberg) |
| 2004-2008 | Special Postdoctoral Researcher, Organometallic Chemistry Laboratory, RIKEN (Director: Dr. Zhaomin Hou) |
| 2009-2011 | Research Scientist, Organometallic Chemistry Laboratory, RIKEN (Director: Dr. Zhaomin Hou) |
| 2011- | Senior Research Scientist, Organometallic Chemistry Laboratory, RIKEN (Director: Dr. Zhaomin Hou) |
| 2013- | Senior Scientist, Advanced Catalysis Research Group, Center for Sustainable Resource Science, RIKEN |
| Original Publications | |
| 30 | Takanori Shima, Shaowei Hu, Gen Luo, Xiaohui Kang, Yi Luo, and Zhaomin Hou; Dinitrogen Cleavage and Hydrogenation by a Trinuclear Titanium Polyhydride Complex, Science 2013, 340, 1549-1552. |
| 29 | Shaowei Hu, Takanori Shima, Yi Luo, and Zhaomin Hou; Tetranuclear Zirconium and Hafnium Polyhydride Complexes Composed of the "CpMH2"Units, Organometallics, 2013, 32, 2145-2151. |
| 28 | Takanori Shima and Zhaomin Hou; Heterometallic Polyhydride Complexes Containing Yttrium Hydrides Bearing Different Cp Ligands: Synthesis, Structure, and Hydrogen Uptake and Release Property, Chem. Eur. J. 2013, 19, 3458-3466. |
| 27 | Masahiro Nagaoka, Takanori Shima, Toshiro Takao, and Hiroharu Suzuki; Synthesis of a heterometallic trinuclear cluster of ruthenium and iridium containing a perpendicularly coordinated alkyne ligand and its dynamic behavior, J. Organomet. Chem. 2013, 725, 68-75. |
| 26 | Takanori Shima, Yi Luo, Timothy Stewart, Robert Bau, Garry J. McIntyre, Sax A. Mason, and Zhaomin Hou; Molecular heterometallic hydride clusters composed of rare-earth and d-transition metals, Nature Chem. 2011, 3, 814-820. |
| 25 | Takanori Shima, Masayoshi Nishiura, and Zhaomin Hou; Tetra-, Penta-, and Hexanuclear Yttrium Clusters from Half-Sandwich Bis(aminobenzyl) Complexes Containing Various Cyclopentadienyl Ligands, Organometallics, 2011, 30, 2513-2524. |
| 24 | Masayoshi Nishiura, Jens Baldamus, Takanori Shima, Kyouichi Mori, and Zhaomin Hou; Snthesis and Structure of the C5Me4SiMe3-Supported Polyhydride Complexes over the Full Size-Range of the Rare Earth Series, Chem. Eur. J. 2011, 17, 5033-5044. |
| 23 | Jianhua Cheng, Takanori Shima, and Zhaomin Hou; Rare-Earth Polyhydride Complexes Bearing Bis(phosphinophenyl)amido Pincer Ligands, Angew. Chem. Int. Ed., 2011, 50, 1857-1860. |
| 22 | Takanori Shima and Zhaomin Hou; Selective ammonolysis of half-sandwich rare-earth metal dialkyl and polyhydride complexes: synthesis of polyamido rare-earth complexes having novel structures, Dalton Trans. 2010, 39, 6858-6863. |
| 21 | Agnieszka J. Nawara-Hultzsch, Katrin Skopek, Takanori Shima, Michal Barbasiewicz, Gisela D. Hess, Dirk Skaper, and John A. Gladysz; Syntheses and Palladium, Platinum, and Borane Adducts of Symmetrical Trialkylphosphines with Three Terminal Vinyl Groups, P((CH2)mCH=CH2)3, Z. Naturforsch., 2010, 65b, 414-424. |
| 20 | Takanori Shima, Kyo Namura, Hajime Kameo, Satoshi Kakuta, and Hiroharu Suzuki; Synthesis and Structure of a Novel Ruthenium Hydrido Bis(dihydrogen) Complex with 1,4,7-Trimethyl-1,4,7-triazacyclononane Ligand: A Useful Precursor for Synthesis of Heterometallic Complexes, Organometallics 2010, 29, 337-346. |
| 19 | Yasumasa Takenaka, Takanori Shima, Jens Baldamus, and Zhaomin Hou; Reduction of Transition -Metal-Coordinated Carbon Monoxide by a Rare-Earth Hydride Cluster: Isolation of Well-Defined Heteromultimetallic Oxycarbene, Oxymethyl, Carbene, and Methyl Complexes, Angew. Chem., Int. Ed. 2009, 48, 7888-7891. |
| 18 | Hajime Kameo, Takanori Shima, Yumiko Nakajima, and Hiroharu Suzuki; Synthesis of Heterometallic Trinuclear Polyhydrido Clusters Containing Ruthenium and Osmium and Their Electronic and Structural Deviation from Homometallic Systems, Organometallics 2009, 28, 2535-2545. |
| 17 | Takanori Shima, and Zhaomin Hou; Rare Earth/d-Transition Metal Heteromultimetallic Polyhydride Complexes Based on Half-Sandwich Rare Earth Moieties, Organometallics 2009, 28, 2244-2252. |
| 16 | Takanori Shima, Yumi Sugimura, and Hiroharu Suzuki; Heterometallic Trinuclear Polyhydrido Complexes Containing Ruthenium and a Group 9 Metal, [Cp*3Ru2M(μ3-H)(μ-H)3] (M = Ir or Rh); Cp* = η5-C5Me5): Synthesis, Structure, and Site-Selectivity in Reactions with Phosphines, Organometallics 2009, 28, 871-881. |
| 15 | Takanori Shima, Zhaomin Hou; Activation and Dehydrogenative Silylation of the C-H Bonds of Ru-Coordinated Phosphines in Lu/Ru Heteromultimetallic Hydride Complexes, Chem. Lett. 2008, 37, 298-299. |
| 14 | Zhaomin Hou, Masayoshi Nishiura, and Takanori Shima; Synthesis and Reactions of Polynuclear Polyhydrido Rare Earth Metal Complexes Composed of "(C5Me4SiMe3)LnH2" Units: A New Frontier of Rare Earth Metal Hydride Chemistry, Eur. J. Inorg. Chem. 2007, 2535-2545. |
| 13 | Takanori Shima, Toshiaki Ichikawa, and Hiroharu Suzuki; Reaction of a Heterobimetallic Polyhydrido Cluster, [Cp*Ru(μ-H)4OsCp*] (Cp* = η5-C5Me5), with Diphenylacetylene. Regioselective C-H Bond Activation at the Osmium Center, Organometallics 2007, 26, 6329-6337. |
| 12 | Florian Jaroschik, Takanori Shima, Xiofang Li, Kyouichi Mori, Louis, Ricard, Xavier-Frederic Le Goff, Francois Nief, and Zhaomin Hou; Synthesis, Characterization, and Reactivity of Mono(phospholyl)Lanthanoid(III) Bis(dimethylaminobenzyl) Complexes, Organometalics 2007, 26, 5654-5660. |
| 11 | Leyong Wang, Takanori Shima, Frank Hampel and J. A. Gladysz; Gyroscope-like molecules consisting of three-spoke stators that enclose “switchable” neutral dipolar rhodium rotators; reversible cycling between faster and slower rotating Rh(CO)I and Rh(CO)2I species, Chem. Commun. 2006, 4075-4077. |
| 10 | Takanori Shima, and Zhaomin Hou; Hydrogenation of Carbon Monoxide by Tetranuclear Rare Earth Metal Polyhydrido Complexes. Selective Formation of Ethylene and Isolation of Well Defined Polyoxo Rare Earth Metal Clusters. J. Am. Chem. Soc. 2006, 128, 8124-8125. |
| 9 | Agnieszka J. Nawara, Takanori Shima, Frank Hampel, and J. A. Gladysz; Gyroscope-like Molecules Consisting of PdX2/PtX2 Rotators Encased in Three-Spoke Stators: Synthesis via Alkene Metathesis, and Facile Substitution and Demetalation. J. Am. Chem. Soc. 2006, 128, 4962-4963. |
| 8 | Jun-ichi Ito, Takanori Shima, and Hiroharu Suzuki; Synthesis of Group 8-Group 6 Heterotrimetallic Polyhydrido Complexes Having Only a C5Me5 Group as Auxiliary Ligand. Organometallics 2006, 25, 1333-1336. |
| 7 | Takanori Shima and Hiroharu Suzuki; Heterobimetallic Polyhydride Complex, Cp*Ru(μ-H)4OsCp* (Cp*=η5-C5Me5). Synthesis, and Reaction with Ethylene. Organometallics 2005, 24, 3939-3945. |
| 6 | Takanori Shima and Hiroharu Suzuki; P-C Bond Cleavage by a Heterobimetallic Polyhydrido Complex, (C5Me5)Ru(μ-H)3Ir(C5Me5). Structure Determination and Fluxional Behavior of a Bridging Phosphido Complex, (C5Me5)Ru(μ-PPh2)(μ-H)(μ-η1:η2-C6H5)Ir(C5Me5). Organometallics 2005, 24, 1703-1708. |
| 5 | Takanori Shima, Frank Hampel, and J. A. Gladysz ; Molecular Gyroscopes Consisting of Fe(CO)3 and Fe(CO)2(NO)+ Rotators Encased in Three-Spoke Stators; Facile Assembly via Alkene Metatheses. Angew. Chem., Int. Ed. 2004, 43, 5537-5540. |
| 4 | Jun-ichi Ito, Takanori Shima, and Hiroharu Suzuki; Di- and Trinuclear Polyhydride Complexes Containing Ruthenium and Rhenium. Synthesis, Site Exchange, and H/D Exchange of Hydride Ligands. Organometallics 2004, 23, 2447-2460. |
| 3 | Takanori Shima, Eike B. Bauer, Frank Hampel, and J. A. Gladysz; Alkene Metatheses in Transition Metal Coordination Spheres: Dimacrocyclizations that join trans Positions of Square-Planar Platinum Complexes to give Topologically Novel Diphosphine Ligands. Dalton Transaction 2004, 1012-1028. |
| 2 | Takanori Shima, Jun-ichi Ito and Hiroharu Suzuki; Synthesis, Characterization and Structure Determination of Heterobimetallic Polyhydride Complexes (C5Me5)Ru(μ-H)3MH3(C5Me5) (M = Mo, W) Containing Group VI and Group VIII Metal. Organometallics 2001, 20, 10-12. |
| 1 | Takanori Shima and Hiroharu Suzuki; Heterobimetallic Polyhydride Complex Containing Ruthenium and Iridium. Synthesis and Site-selectivity in the Reaction with Unsaturated Hydrocarbons. Organometallics 2000, 19, 2420-2422. |
| 略歴 | >> English |
| 1996年3月 | 東京工業大学工学部化学工学科卒 |
| 1998年3月 | 東京工業大学大学院理工学研究科化学工学専攻修士課程修了 |
| 1998年4月 ～2001年3月 |
日本学術振興会特別研究員（DC1） |
| 2001年3月 | 東京工業大学大学院理工学研究科化学工学専攻博士課程修了 博士取得 学位論文『異種金属を含む多核ポリヒドリド錯体の合成と反応』 |
| 2001年4月 | 科学技術振興事業団CREST博士研究員 |
| 2002年12月 | エアランゲン大学 (ドイツ) 博士研究員 |
| 2003年7月 | ドイツ･フンボルト財団博士研究員 |
| 2004年5月 | 独立行政法人 理化学研究所 協力研究員 |
| 2004年10月 | 独立行政法人 理化学研究所 基礎科学特別研究員 |
| 2007年10月 | 独立行政法人 理化学研究所 協力研究員 |
| 2009年10月 | 独立行政法人 理化学研究所 研究員 |
| 2011年4月 ～現在 |
独立行政法人 理化学研究所 侯有機金属化学研究室 専任研究員 |
| 2013年4月 ～現在 |
独立行政法人 理化学研究所 環境資源科学研究センター 先進機能触媒研究グループ 上級研究員 兼務 |
| 兼務 | |
| 2006年1月 ～2007年1月 |
東京農工大非常勤講師 |
| 2011年1月 | 埼玉大学大学院連携大学院セミナー非常勤講師 |
| 受賞歴 | |
| 2001年度 | 手島研究賞博士論文賞｢異種金属を含む多核ポリヒドリド錯体の合成と反応(東京工業大学) |
| 2007年10月 | 第1回日本化学会関東支部大会優秀講演賞｢希土類金属とd-ブロック遷移金属を含む混合型ヒドリド錯体の合成及び可逆的な水素吸蔵特性」(日本化学会関東支部） |
| 2007年12月 | 理化学研究所理事長感謝状(野依良治理事長) |
| 2008年1月 | 理化学研究所基礎科学特別研究員成果発表ポスター賞（茅幸二中央研所長) |
| 2008年3月 | 第22回｢若い世代の特別講演会」講演:｢分子性希土類ヒドリドクラスターの特異な反応性」(日本化学会) |
| 2008年7月 | 理化学研究所理事長感謝状(野依良治理事長) |
| 2012年3月 | 理化学研究所 研究奨励賞 |
| 言語 | 日本語（母国語）、英語（良） |
| その他 | 日本化学会(1996-)、錯体化学会(2006-)、日本希土類学会(2008-)、危険物取扱者(甲種)、高圧ガス製造保安責任者(乙種化学)、ゼネラル石油奨学会奨学生 (1995-1998)、102nd BASF International Summer Course (Germany) 参加 (2001)、第56回リンダウ会議(ノーベル化学賞受賞者会議)参加(2006年、ドイツ)、RIKEN NEWS(2008年11月号） |