Research Summary

Selected Publications

• 1.Sumida, Y., Sumida, T., Hosoya, T.:
  "Nickel-Catalyzed Reductive Cross-Coupling of Aryl Triflates and Nonaflates with Alkyl Iodides"
  Synthesis, 49 (16), 3582–3589 (2017).
• 2.Niwa, T., Ochiai, H., Isoda, M., Hosoya, T.:
  "Facile Transformation of α,β-Unsaturated Carboxylic Acids to Alkenylboronic Esters via Rhodium-Catalyzed Decarbonylative Borylation of α,β-Unsaturated Thioesters"
  Chem. Lett. 46 (9), 1315–1318 (2017).
• 3.Niwa, T., Ochiai, H., Hosoya, T.:
  "Copper-Catalyzed ipso-Borylation of Fluoroarenes"
  ACS Catal. 7(7), 4535-4541 (2017).
• 4.Ochiai, H., Uetake, Y., Niwa, T., Hosoya, T.:
  "Rhodium-Catalyzed Decarbonylative Borylation of Aromatic Thioesters for Facile Diversification of Aromatic Carbocyclic Acids"
  Angew. Chem., Int. Ed. 56(9), 2482-2486 (2017).
• 5.Ochiai, H., Niwa, T., Hosoya, T.:
  "Stereoinversion of Stereocongested Carbocyclic Alcohols via Triflylation and Subsequent Treatment with Aqueous N,N-Dimethylformamide"
  Org. Lett. 18(23), 5982-5985 (2016).
• 6.Sumida, Y., Sumida, T., Hashizume, D., Hosoya, T.:
  "Preparation of Aryne-Nickel Complexes from ortho-Borylaryl Triflates"
  Org. Lett. 18(21), 5600-5603 (2016).
• 7.Uetake, Y., Niwa, T., Hosoya, T.:
  "Rhodium-Catalyzed ipso-Borylation of Alkylthioarenes via C-F Bond Cleavage"
  Org. Lett. 18(11), 2758-2761 (2016)
  
• 8.Niwa, T., Ochiai, H., Watanabe, Y., Hosoya, T.:
  "Ni/Cu-Catalyzed Defluoroborylation of Fluoroarenes for Diverse C-F Bond Functionalization"
  J. Am. Chem. Soc. 137(45), 14313-14318 (2015).
• 9.Takahashi, K., Hosoya, T., Onoe, K., Doi, H., Nagata, H., Hiramatsu, T., Li, X. L., Watanabe, Y., Wada, Y., Takashima, T., Suzuki, M., Onoe, H., Watanabe, Y.:
  "[¹¹C]Cetrozole: an Improved C-[¹¹C]Methylated PET Probe for Aromatase Imaging in the Brain."
  J. Nucl. Med. 55(5), 852-857 (2014).
  
• 10.Takahashi, K., Yamagishi, G., Hiramatsu, T., Hosoya, A., Onoe, K., Doi, H., Nagata, H., Wada, Y., Onoe, H., Watanabe, Y., Hosoya, T.:
  "Practical synthesis of precursor of [N-methyl-¹¹C]vorozole, an efficient PET tracer targeting aromatase in the brain."
  Bioorg. Med. Chem. 19(4), 1464-1470 (2011).

Recent Research Results

• 

  Aug. 30, 2019
  Doubling down on boron to make complex organic molecules

Related Links

Lab Members

Contact Information