RIKEN Center for Advanced Photonics Ultrafast Spectroscopy Research Team
Team Leader: Tahei Tahara (D.Sc.)
Research Summary
We develop advanced spectroscopic methods based on the "extreme" optical technology, and carry out fundamental studies for controlling chemical reactions and material functions. We pursue the basic knowledge for developing novel functional materials by investigating the elementary processes that occur in fundamental molecules, complex molecules, and heterogeneous molecular systems. Using the most advanced spectroscopy, we observe and control the motion and function of the molecules.
Main Research Fields
- Chemistry
Related Research Fields
- Mathematical & Physical Sciences
- Biology
- Physical chemistry
- Biological physics/Chemical physics/Soft matter physics
- Biophysics
Keywords
- Ultrafast spectroscopy
- Nonlinear spectroscopy
- Single molecule spectroscopy
- Dynamics
- Interface
Selected Publications
- 1.Kuramochi, H., Tsutsumi, T., Saita, K., Wei, Z., Osawa, M., Kumar, P., Liu, L., Takeuchi, S., Taketsugu, T., Tahara, T.:
"Ultrafast Raman observation of the perpendicular intermediate phantom state of stilbene photoisomerization"
Nat. Chem. 16, 22-27 (2024). - 2.Sung, W., Inoue, K., Nihonyanagi, S., Tahara. T.:
"Unified picture of vibrational relaxation of OH stretch at the air/water interface"
Nat. Commun. 15, 1258/1-11 (2024). - 3.Kumar, P., Kuramochi, H., Takeuchi, S., Tahara, T.:
"Photoexcited plasmon-driven ultrafast dynamics of the adsorbate probed by femtosecond time-resolved surface-enhanced time-domain Raman spectroscopy"
J. Phys. Chem. Lett. 14, 2845-2853 (2023). - 4.Chang, C., Kuramochi, H., Singh, M., Abe-Yoshizumi, R., Tsukuda, T., Kandori, H., Tahara, T.:
“A unified view on varied ultrafast dynamics of the primary process in microbial rhodopsins”
Angew. Chem. Int. Ed. 61, e202111930/1-9 (2022). - 5.Kusaka, R., Nihonyanagi, S., Tahara, T.:
"The photochemical reaction of phenol becomes ultrafast at the air-water interface"
Nat. Chem. 13, 306-311 (2021). - 6.Ahmed, M., Inoue, K., Nihonyanagi, S., Tahara, T.:
"Hidden isolated OH at the charged hydrophobic interface revealed by two-dimensional heterodyne-detected VSFG spectroscopy"
Angew. Chem. Int. Ed. 59, 9498-9505 (2020). - 7.Inoue, K., Ahmed, M., Nihonyanagi, S., Tahara, T.:
"Reorientation-induced relaxation of free OH at the air/water interface revealed by ultrafast heterodyne-detected nonlinear spectroscopy"
Nat. Commun. 11, 5344/1-7 (2020). - 8.Iwamura, M., Fukui, A., Nozaki, K., Kuramochi, H., Takeuchi, S., Tahara, T.:
"Coherent vibration and femtosecond dynamics of the platinum complex oligomers upon intermolecular bond formation in the excited state"
Angew. Chem. Int. Ed. 59, 23154-23161 (2020). - 9.Kuramochi, H., Takeuchi, S., Kamikubo, H., Kataoka, M., Tahara, T.:
"Fifth-order time-domain Raman spectroscopy of photoactive yellow protein for visualizing vibrational coupling in its excited state"
Sci. Adv. 5, eaau4490/1-7 (2019). - 10.Tahara, S., Kuramochi, H., Takeuchi, S., Tahara, T.:
"Protein dynamics preceding photoisomerization of the retinal chromophore in bacteriorhodopsin revealed by deep-UV femtosecond stimulated Raman spectroscopy"
J. Phys. Chem. Lett. 10, 5422-5427 (2019).
Recent Research Results
-
Jun. 21, 2024
How molecules at the surface of water relax
Related Links
Lab Members
Principal investigator
- Tahei Tahara
- Team Leader
Core members
- Kunihiko Ishii
- Senior Research Scientist
- Satoshi Nihonyanagi
- Senior Research Scientist
- Korenobu Matsuzaki
- Research Scientist
- Jan-Hendrik Georg Guenther Borter
- Postdoctoral Researcher
Contact Information
2-1 Hirosawa, Wako, Saitama 351-0198, Japan
Email: tahei@riken.jp