We develop new instruments/methods and novel science so as to exploit capabilities of brilliant synchrotron radiation at seven RIKEN beamlines for physics and chemistry (BL05XU, BL17SU, BL19LXU, BL29XU, BL32B2, BL36XU, BL44B2). Furthermore, the technologies developed here will be utilized for promoting upgrades of the whole SPring-8 beamlines that connects SPring-8-II, the next-generation, ultrabrilliant synchrotron source.