研究概要

主要論文

• 1. Shima, T., Zhuo, Q., Zhou, X., Wu, P., Owada, R., Luo, G., and Hou, Z.:
  "Hydroamination of alkenes with dinitrogen and titanium polyhydrides"
  Nature., 632, 307-312. (2024)
• 2. Zhou, X., Zhuo, Q., Shima, T., Kang, X., and Hou, Z.:
  "Denitrogenative Ring-Contraction of Pyridines to a Cyclopentadienyl Skeleton at a Dititanium Hydride Framework“
  J. Am. Chem. Soc, 146, 31348–31355 (2024)
• 3. Cong, X., Hao, N., Mishra, A., Zhuo, Q., An, K., Nishiura, M., and Hou, Z.:
  "Regio- and Diastereoselective Annulation of α,β-Unsaturated Aldimines with Alkenes via Allylic C(sp3)–H Activation by Rare-Earth Catalysts"
  J. Am. Chem. Soc., 146,10187-10198 (2024)
• 4. Huang, L., Yang, Y., Shao, J., Xiong, G., Wang, H., Nishiura, M., and Hou, Z.:
  "Synthesis of Tough and Fluorescent Self-Healing Elastomers by Scandium-Catalyzed Terpolymerization of Pyrenylethenylstyrene, Ethylene, and Anisylpropylene"
  J. Am. Chem. Soc., 146, 2718-2727. (2024)
• 5. Zhuo, Q., Yang, J., Zhou, X., Shima, T., Luo, Y., and Hou, Z.:
  "Aza-Michael Addition of Dinitrogen to α, β-Unsaturated Carbonyl Compounds in a Dititanium Framework"
  J. Am. Chem. Soc., 145, 22803-22813. (2023)
• 6. Wang, H., Yang, Y., Nishiura, M., Hong, Y., Nishiyama, Y., Higaki, Y., and Hou, Z.:
  "Making Polyisoprene Self-Healable through Microstructure Regulation by Rare-Earth Catalysts",
  Angew. Chem. Int. Ed., 61, e202210023. (2022)
• 7. Lou, S., Luo, G., Yamaguchi, S., An, K., Nishiura, M., and Hou, Z.:
  "Modular Access to Spiro-dihydroquinolines via Scandium-Catalyzed Dearomative Annulation of Quinolines with Alkynes"
  J. Am. Chem. Soc., 143, 20462-20471. (2021)
• 8. Wang, H., Yang, Y., Nishiura, M., Higaki, Y., Takahara, A., Hou, Z.:
  "Synthesis of Self-Healing Polymers by Scandium-Catalyzed Copolymerization of Ethylene and Anisylpropylenes"
  J. Am. Chem. Soc. 141, 3249-3257 (2019).
• 9. Hu, S., Shima, T., and Hou, Z.:
  "Carbon-Carbon Bond Cleavage and Rearrangement of Benzene by a Trinuclear Titanium Hydride"
  Nature, 512, 413-415 (2014).
• 10. Shima, T., Hu, S., Luo, G., Kang, X., Luo, Y., and Hou, Z.:
  "Dinitrogen Cleavage and Hydrogenation by a Trinuclear Titanium Polyhydride Complex"
  Science, 340, 1549-1552 (2013).

研究成果（プレスリリース）

• 

  2023年10月18日
  窒素分子からヒドラジン誘導体作製に成功

• 

  2022年4月8日
  窒素分子と二酸化炭素から有機物を合成

• 

  2016年5月20日
  機能性ポリマーの新しい合成法を開発

• 

  2016年4月13日
  リチウムホウ素化合物の新しい合成法を開発

• 

  2016年3月15日
  有機ケイ素化合物の新しい合成法を開発

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